Hot atom chemistry and radiolysis of gaseous and solid components of planetary atmospheres.

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Planetary Atmospheres:Chemistry, Planetary Atmospheres:Laboratory Simulations

Scientific paper

Particles with kinetic energies exceeding a few eV are relatively frequent in space. They induce chemical reactions different from those considered in cosmic chemistry hitherto and include endothermic reactions with high activation energies and atom-molecule interactions. This "hot atom chemistry" leads to the formation of molecules in rings and icy surfaces as well as in the upper atmosphere of planets and satellites. An important contribution comes from secondary particles generated by cosmic rays in the deeper layers of the atmospheres and the oceans. Laboratory simulation is performed by ion implantation and optical spectroscopy, chemical sputtering and mass spectroscopy, as well as by nuclear recoil techniques and radiochromatography. The variation of the chemical products with the radiation dose gives information on radiation chemistry in space.

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