Mineralogy, chemistry, and oxygen isotopes of refractory inclusions from stratospheric interplanetary dust particles and micrometeorites

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Scientific paper

Ca,Al-rich inclusions (CAIs) are characteristic components in carbonaceous chondrites. Their mineralogy is dominated by refractory oxides and silicates like corundum, perovskite, spinel, hibonite, melilite, and Ca-pyroxene, which are predicted to be the first phases to have condensed from the cooling solar nebula. Allowing insights into processes occurring in the early solar system, CAIs in carbonaceous and ordinary chondrites were studied in great detail, whereas only a few refractory inclusions were found and studied in stratospheric IDPs and micrometeorites. This study gives a summary of all previous studies on refractory inclusions in stratospheric IDPs and micrometeorites and will present new data on two Antarctic micrometeorites. The main results are summarized as follows: a) Eight stratospheric IDPs and six micrometeorites contain Ca,Al-rich inclusions or refractory minerals. The constituent minerals include spinel, perovskite, fassaite, hibonite, melilite, corundum, diopside and anorthite, b) Four of the seven obtained REE patterns from refractory objects in stratospheric IDPs and micrometeorites are related to Group III patterns known from refractory inclusions from carbonaceous chondrites. A Group II related pattern was found for spinel and perovskite in two micrometeorites. The seventh REE pattern for an orthopyroxene is unique and can be explained by fractionation of Gd, Lu, and Tb at highly reducing conditions, c) The oxygen isotopic compositions of most refractory objects in stratospheric IDPs and micrometeorites are similar to those of constituents from carbonaceous chondrites and fall on the carbonaceous chondrites anhydrous minerals mixing line. In far the most cases mineralogy, REE pattern and oxygen isotope composition of refractory inclusions in stratospheric IDPs and micrometeorites are in good agreement with a suggested genetic relation of dust particles and carbonaceous chondrites. Only in case of one Antarctic micrometeorite the REE pattern obtained for an orthopyroxene may point to a link of this particle to enstatite chondrites.

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