The evolution of atmospheric CO2 on Mars - The perspective from carbon isotope measurements

Mathematics – Logic

Scientific paper

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Carbon Dioxide, Carbon Isotopes, Mars Atmosphere, Viking Mars Program, Carbonates, Isotope Effect, Kinetic Equations, Mars Surface, Meteorites, Silicates

Scientific paper

Assuming that SNC meteorites derive from Mars, the evolution of atmospheric CO2 on Mars is investigated using literature data on C-13 isotope from SNC meteorites. High-precision isotopic measurements show that there is a 40 vol pct fractionation between carbon associated with silicate minerals and the trapped CO2 gas or carbonate minerals. Trapped CO2 is considered to be a sample of Martian atmospheric gas. The significant difference in isotopic composition between the different components in SNC meteorites was difficult to interpret in terms of closed-system equilibrium or kinetic isotopic fractionation effects. It is suggested that the relative C-13 enrichment in surficial carbon is due to preferential removal of the lighter isotope during an atmospheric loss process.

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