Astronomy and Astrophysics – Astrophysics
Scientific paper
Dec 2009
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009aspc..417..439d&link_type=abstract
Submillimeter Astrophysics and Technology: a Symposium Honoring Thomas G. Phillips ASP Conference Series, Vol. 417, proceedings
Astronomy and Astrophysics
Astrophysics
Scientific paper
It is well known that many, if not most, of the unidentified features in astrophysical spectra arise from relatively low lying excited vibrational and torsional states of a relatively small number of molecular species— the astrophysical weeds. It is also well known that the traditional quantum mechanical assignment and fitting of these excited state spectra is a formidable task, one that is made harder by the expected perturbations and interactions among these states. We have previously proposed an alternative fitting and analysis approach based on experimental, intensity calibrated spectra taken at many temperatures. In this paper we discuss the implementation of this approach and provide details in the context of one of these weeds, ethyl cyanide.
de Lucia Frank C.
Fortman Sarah M.
Medvedev Ivan R.
Neese Christopher F.
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