Computer Science
Scientific paper
Oct 1998
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1998stin...9921045p&link_type=abstract
Technical Report, Arizona State Univ. Tempe, AZ United States Dept. of Chemistry and Biochemistry
Computer Science
Amino Acids, Murchison Meteorite, Carbonaceous Chondrites, Acetic Acid, Water, Glutamic Acid, Contamination, Alanine
Scientific paper
Amino acids present in carbonaceous chondrite are extracted in water in part as free compounds and in approximately equal part as acid labile precursors. On the assumption that they would be free of contamination, the precursors of two Murchison amino acids that have terrestrial occurrence, alanine and glutamic acid, have been targeted for analysis of their enantiomeric ratios. Pyroglutamic acid, the precursor of glutamic acid, was found with an L-enantiomeric excess comparable to that of the free acid, while alanine's precursor, N-acetyl alanine, appears approximately racemic. Also alpha-imino propioacetic acid, a proposed end product of alanine synthesis in the meteorite, was analyzed and found racemic.
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