Statistics – Applications
Scientific paper
Jul 1993
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1993jgr....9813119w&link_type=abstract
Journal of Geophysical Research (ISSN 0148-0227), vol. 98, no. E7, p. 13,119-13,136.
Statistics
Applications
8
Atmospheric Chemistry, Photochemical Reactions, Photodissociation, Photolysis, Planetary Atmospheres, Quantum Efficiency, Acetylene, Airglow, Ammonia, Carbon Dioxide, Ozone, Rotational Spectra, Vibrational Spectra, Planets, Atmosphere, Photodissociation, Dynamic, Chemistry, Energy, Laboratory Studies, Ozone, Molecules, Dissociation, Fragmentation, Vibration, Rotation, Photolysis, Structure, Parent Material, Spectra, Experiments, Outer Planets, Gas Planets, Satellites, Emissions, Parameters, Carbon Dioxide,
Scientific paper
The paper uses data from the literature to explore photodissociation dynamics of molecules possessing three, four, and five atoms, as represented by O3 and CO2, NH3 and C2H2, and CH4, respectively. The results yield many details, even in regard to the disposal of energy into rotation, which have applications to atmospheric problems. For instance, experiments probing the translational energies of the O and the vibrational and rotational distributions in the CO suggest that a spin-forbidden channel operates as it does in ozone photolysis. The data for both O3 and CO2 suggest a relationship between the structure of the parent molecule and the dynamics of dissociation.
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