Elemental depletions in the interstellar medium

Mathematics – Probability

Scientific paper

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Astronomical Models, Atomic Recombination, Depletion, Interstellar Matter, Recombination Reactions, Aluminum, Boron, Calcium, Cations, Chemical Properties, Chromium, Copper, Elements, Grains, Ionic Collisions, Iron, Magnesium, Manganese, Silicon Dioxide, Titanium

Scientific paper

A model for the reaction of positive ions with negatively charged species on oxide grain surfaces is proposed which involves recombination of a gas-phase ion with surface O(-) or OH(-). The excess energy associated with this reaction is shown to generate surface transitions similar to those responsible for the 2175-A extinction feature. When this excess energy is close to 5.7 eV, the ion is retained by the grain surface. If the excess energy differs by more than (+ 1.0, -1.5) eV from 5.7 eV, the probability that the element is retained is small. This leads to selective depletion of Al, Ca, Cr, Ti, Mn, Mg, Ni, Cu, Fe, Si, and B. These selective effects are shown to arise when ions collide with small grains. Larger grains are responsible for a uniform depletion experienced by all elements. Overall depletions are the result of both mechanisms. Comparison of the depletion of a selectively depleted element such as Ca with that of an element such as Na that is not selectively depleted leads to an estimate of the radii of the two grain types.

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