Sulphur isotope exchange between sulphur dioxide and hydrogen sulphide

Details Sulphur isotope exchange between sulphur dioxide and hydrogen sulphide Sulphur isotope exchange between sulphur dioxide and hydrogen sulphide

Jan 1971

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1971gecoa..35...35t&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 35, Issue 1, pp.35-45

Computer Science

3

Scientific paper

The variation with absolute temperature, T , of the sulphur isotope equilibrium constant, K , between sulphur dioxide and hydrogen sulphide has been measured and the results compared with theoretical calculations. In the temperature range 800°K to 1300°K the experimentally measured variation is ( K - 1) = (4540/ T 2 ) - 0.0003, while the theoretically calculated variation is ( K - 1) = (3650/ T 2 ). These two estimates do not quite overlap within the assigned limits of error but theory and experiment agree to within 1%. in the temperature range studied. Thus geochemical calculations involving this exchange reaction may be performed with confidence using either estimate for the isotope equilibrium constant.

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